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姓名： 郭生梅

性别： 男

职称： 教授

学位： 博士

专业：化学

电子邮箱：smguo@ncu.edu.cn

研究方向： 有机合成，绿色合成

教育工作经历

2012.09~至今: 南昌大学化学学院从事教学科研工作，硕导

2017.01~2018.01：加州大学圣地亚哥分校(合作导师：Prof. Guy Bertrand，国家公派访问学

2008.09~2012.01：中科院兰州化学物理研究所，获博士学位

2005.09~2008.06：湖南师范大学，获硕士学位

2001.07~2005.06：江西省汤湖中学，中学教师

1998.09~2001.06：井冈山大学(井冈山师范学院)

教学简介:

担任《有机化学》，《有机化学实验》，《绿色化学》等本科生课程的教学。

科研简介：

一直从事有机合成、绿色催化方面的研究。主持国家自然科学基2项，省自然科学基金2项，发表论文SCI 论文60于篇。

科研项目

1. 国家自然科学基金地区项目：叠氮促进的N,N-二烷基酰胺电化学转化研究(22361029, 2024-2027)；

2. 国家自然科学基金地区项目：Csp3-P及Csp2-P键的选择性构建(21861024, 2019-2022)；

3. 江西省自然科学基金面上项目：卡式盐的脱氨还原偶联反应构建Csp3-杂键(20232BAB203008, 2023-2026)；

4. 国家自然科学基金青年项目：基于亚甲基桥联类化合物的绿色合成(21302084, 2014-2016);

5. 江西省自然科学基金青年项目：过渡金属催化的C-H官能化构建C-P键的反应研究(20151BAB213007, 2015-2016).

社会兼职

获奖情况

代表性论文及专利

1. Li H, Li S, Hu H, et al. Visible-light-induced C(sp3)–C(sp3) bond formation via radical/radical cross-coupling. Chem. Commun., 2023, 59, 1205-1208.

2. Liu M, Hu H, Sun R, et al. Nickel-catalyzed reductive coupling of nitroarenes and phosphine oxides to access phosphinic amides. Org. Chem. Front., 2023, 10, 5478-5483

3. Luo W, Zhang R, Xu Q, et al. Trimethylsilyl Azide Promoted Shono Oxidation of N,N -Dialkyl Amides. Synlett., 2023, 34, 2346-2350

4. Guo S, Yan W, Zhang Z, et al. Nickel-Catalyzed 1,1-Dihydrophosphinylation of Nitriles with Phosphine Oxides. J. Org. Chem. 2022, 87, 5522-5529

5. Li H, Yan W, Ren P, et al. Bromide ion promoted practical synthesis of phosphinothioates of sulfinic acid derivatives and H-phosphine oxides. RSC Adv., 2022, 12, 32350-32354

6. Guo S, Li S, Yan W, et al. Environmentally sustainable production and application of acyl phosphates. Green. Chem., 2020, 22, 7343-7347

7. Li S, Jie K, Yan W, et al. Selective C-C bond cleavage of amides fused to 8-aminoquin- oline controlled by a catalyst and an oxidant. Chem. Commun., 2020, 56, 13820-13823.

8. Guo S, Li S, Zhang Z, et al. Electrochemical selenation of phosphonates and phosphine oxides. Tetrahedron Lett., 2020, 61, 151566

9. Huang Z, Liu W, Li S, et al. Potassium Carbonate Promoted Nucleophilic Addition of Alkenes with Phosphites. Synlett., 2020, 31, 1295-1297

10. Guo S, Jie K, Huang L, et al. Fe-Catalyzed Bisphosphorylation of Amino-2-en-1- ones with Trialkyl Phosphites. Synlett., 2019, 30, 1090-1094

11. Guo S, Jie K, Zhang Z, et al. Regioselective C3-Phosphonation of Free Indoles via Transition-Metal-Free Radical/Hydrolysis Cascade. Eur. J. Org. Chem., 2019, 1808-1814

12. Guo S, Zhang Z, Xu J, et al. Acid and 1, 2-Dichloroethane Co-Promoted Substitution of the Amino Groups in Gramine and its Analogues with Trialkyl Phosphites. ChemistrySelect., 2019, 4, 14111-14113.

13. Huang L, Zhang Z, Jie K, et al. Nucleophile-controlled mono- and bis- phosphonation of amino-2-en-1-ones via catalyst-free C(sp3 )-N bond cleavage. Org. Chem. Front., 2018, 5, 3548-3552

14. Wang Y, Yang Y, Jie K, et al. Copper-Catalyzed C2 and C3 Phosphonation of Benzo- furan and Benzothiophene with Trialkyl Phosphites. ChemCatChem., 2018, 10, 716-719

15. Huang L. Gong J. Guo S. Cai H. et al. Selective Phosphoramidation and Phosphonation of Benzoxazoles via Sequence Control. Org. Lett., 2017, 19, 2242-2245

16. Gong, J. Huang, L. Guo, S. Cai, H. et al. Metal-free phosphonation of benzoxazoles and benzothiazoles under oxidative conditions. Org. Chem. Front., 2017, 4, 1781-1784

17. Huang, L. Guo, S. Cai, H. Rapid, practical and efficient synthesis of enol phosphates from β-keto esters and phosphites. Chin. J. Org. Chem., 2017, 37, 2571-2576

授权专利：

一种三杂芳基叔胺及三杂芳基叔胺的合成方法ZL 202310233612.4

职位