南昌大学化学化工学院
Chinese

Professor

蔡琥

2023-09-04

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Name: Cai Hu

Gender: Male

Job title: Professor

Email Address: caihu@ncu.edu.cn

Education:

September, 1996 – June, 1999; Nanjing University, China, Ph.D. in Inorganic Chemistry, “Synthesis and Crystal Structures of Micro-porous Silver(I) Coordination Polymers”.

September, 1993 – June, 1996; Nanjing University, China, M.S. in Organic Chemistry, “Photo-induced Electron Transfer Reactions of Phthalimide Derivatives with Organic Amines”.

September, 1986 – June, 1990; Lanzhou University, China, B.S. in Organic Chemistry.

Work Experience

June, 2007 – present; School of Chemistry and Chemical Engineering, Nanchang University, China; Dean, Ganjiang Professor, Xiangzhang Distinguished Professor;

April, 2004 – May, 2007; Center for Environmentally Beneficial Catalysis, University of Kansas, United States; Postdoctoral research associate;

November, 2002 – March 2004; Department of Chemistry, Case Western Reserve University; United States; Research associate;

June, 1999 – October, 2002; Department of Chemistry, University of Tennessee at Knoxville, United States; Postdoctoral research associate:

June, 1990 August, 1993; Jiangxi Xinyu Iron & Steel Company, China; Assistant engineer;

TeachingOrganic Chemistry, Green Chemistry, Organometallic Chemistry, Modern Organic Synthesis;

Research fields:

Organic synthesis, organic-inorganic hybrid functional molecules.

Research projects

  1. Design, synthesis and performance study of a novel stator rotor type metal free molecular ferroelectric material. National Natural Science Foundation of China, Under research, 2021-2024.

  2. Coordination polymers constructed from organic nitrogen hydroxyl compounds and their functional properties. National Natural Science Foundation of China, Conclusion, 2016-2019.

  3. Study on Transition Metal Catalyzed Hydrogen Ammonia Alkylation Reaction. National Natural Science Foundation of China, Under research, 2019-2022.

  4. Study on the Synthesis and Reaction of High Valence VB Group Transition Metal Nitrogen Heterocyclic Carbene Compounds. Conclusion, 2012-2015.

  5. Basic research on the sub topic of "Scientific Foundation for Efficient Utilization and Green Separation of Rare Earth Resources" - "Recovery of Extremely Low Content Rare Earth Solutions from Southern Ionic Mines". Conclusion, 2012-2016.

Awards and Honors

1. Xiangzhang Distinguished Professor

2. Jiangxi Province's "Double Thousand Plan"

3. The New Centuary National Hundred, Thousand and Ten Thousand Talent Project

Representative papers and patents

1. Rational design of ceramic-like molecular ferroelectric by quasi- spherical theory. Wei, Zhen-Hong; Jiang, Zhen-Tao; Zhang, Xiu-Xiu; Li, Ming- Li; Tang, Yuan-Yuan; Chen, Xiao-Gang; Cai, Hu*; Xiong, Ren-Gen*. Journal of the American Chemical Society, 2020, 142(4), 1995-2000.

2. Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides. Fu, Zhengjiang; Hao, Guangguo; Fu, Yaping; He, Dongdong; Tuo, Xun; Guo, Shengmei; Cai, Hu*. Organic Chemistry Frontiers 2020, 7(3), 590-595.

3. Pd-Catalyzed Decarboxylative Ortho-Halogenation of Aryl Carboxylic Acids with Sodium Halide NaX Using Carboxyl as a Traceless Directing Group. Fu, Zhengjiang; Jiang, Yongqing; Wang, Shuiliang; Song, Yuanyuan; Guo, Shengmei; Cai, Hu*. Organic Letters, 2019, 21(9), 3003-3007.

4. Nucleophile-controlled mono- and bis-phosphonation of amino-2- en-1-ones via catalyst-free C(sp3)-N bond cleavage. Huang, Ling; Zhang, Zhebin; Jie, Kun; Wang, Yufeng; Fu, Zhengjiang; Guo, Shengmei; Cai, Hu*. Organic Chemistry Frontiers 2018,5(24),3548-3552.

5. Narrowest Band Gap Ever Observed in Molecular Ferroelectrics: Hexane -1,6-diammonium Pentaiodobismuth(III). Zhang, Han-Yue; Wei, Zhenhong; Li, Peng-Fei ; Tang, Yuan-Yuan; Liao, Wei-Qiang; Ye, Heng-Yun; Cai, Hu*; Xiong, Ren-Gen*; Angewandte Chemie, International Edition, 2018 , 57(2), 526-530.

6. Metal-free phosphonation of benzoxazoles and benzothiazoles under oxidative conditions. Gong, Jiuhan; Huang, Ling; Deng, Qidu; Jie, Kun; Wang, Yufeng; Guo, Shengmei*; Cai, Hu*; Organic Chemistry Frontiers, 2017, 4(9), 1781-1784.

7. Selective phosphoramidation and phosphonation of benzoxazoles via sequence control. Huang, Ling; Gong, Jiuhan; Zhu, Zheng; Wang, Yufeng; Guo, Shengmei*; Cai, Hu*; Organic Letters, 2017, 19(9), 2242-2245.

8. Halogenation and Cyanation of Electron-Deficient Aryl Carboxylic Acids via Cu Mediator as Well as Electron-Rich Ones through Pd Catalyst under Aerobic Conditions, Fu, Zhengjiang; Li, Zhaojie; Song, Yuanyuan; Yang, Ruchun; Liu, Yanzhu; Cai, Hu*; Journal of Organic Chemistry; 2016, 81(7), 2794-2803.

9. Palladium-Catalyzed Decarboxylative Methylthiolation of Aromatic Carboxylic Acids by Using DMSO as the Sulfurizing Reagent. Fu, Zhengjiang; Li, Zhaojie; Xiong, Qiheng; Cai, Hu*. European Journal of Organic Chemistry, 2014, 2014(35), 7798-7802.

10. C-H Bond Activation during and after the Reactions of a Metallacyclic Amide with Silanes : Formation of a μ-Alkylidene Hydride Complex , Its H -D Exchange , and B-H Abstraction by a Hydride Ligand. Wang, Li; Hunter, Seth C; Song, Zhimin; Steren, Carlos A; Chen, Tianniu; Wei, Zhenhong; Cai, Hu*; Xue, Zi-Ling*. Chemistry-A European Journal, 2014, 20(20), 6033-6039.

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